缅北禁地

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Staff Profile

Emeritus Professor Anthony Harriman

Emeritus Professor

  • Telephone: 07717256876
  • Personal Website: under development
  • Address: Professor Anthony Harriman
    Molecular Photonics Laboratory
    School of Natural and Environmental Sciences
    Bedson Building
    缅北禁地
    缅北禁地 upon Tyne
    NE1 7RU
    United Kingdom
Background

Background

Despite 50 years of continuous experimental work and in excess of 400 publications, there are still many areas of applied molecular photophysics that attract deep interest. In fact, the two research topics that were my introduction to the field, namely the development of photodegradable plastics and artificial photosynthesis, remain unsolved and as significant as ever. In part, progress in these areas is hindered by a desire to understand mechanisms, probabilities and reaction rates at the expense of producing a workable solution. This is certainly true in my case, although patents have been issued for an artificial photosynthetic device (with Lord George Porter), effective photobleaches that operate at low temperature (with the Procter & Gamble Co.), and pressure-sensitive anti-counterfeit systems (with the Bank of England). The real interest, however, lies with identifying intermediate species in photochemical processes, especially those related to natural photosynthesis, and in manipulating environmental effects to engineer high levels of photo-selectively.

No longer involved in undergraduate teaching, pedagogical matters take the form of writing a monograph on Colligative Properties, with lots of example calculations. There is also time to learn how to apply matrix theory and phasor methods for better representing multi-component photophysical processes. A book on Artificial Light-Harvesting Networks is slowly taking shape. I am actively involved in Advisory Boards, Editorial Boards and Review Boards.

The Annual Daedalus Lecture is organised jointly with Prod Bernard Golding and recognises the outstanding contributions to the public awareness of science made by Dr. David Jones. The lecture is intended for an interactive audience and is on-hold until restrictions imposed by COVID-19 have eased. The two previous lectures were given by Sir Martyn Poliakoff and Prof. David Leigh. Details for the next lecture will be announced once the situation has stabilised.

Please note that I am not taking any new students or postdoctoral associates into my research group. Suggestions for potential collaborations are always welcome.

Qualifications

PhD
Grad RIC
HNC
ONC

Previous Positions

SRC Postdoctoral Fellow, The Royal Institution, London, U.K. 1974-75
EEC Postdoctoral Fellow, The Royal Institution, London, U.K. 1975-77
Dewar Research Fellow, The Royal Institution, London, U.K. 1977-88
Assistant Director, The Royal Institution, London, U.K. 1980-88
Visiting Scientist, National Bureau of Standards, Washington, D.C., U.S.A. 1985-86
Deputy Director, Center for Fast Kinetics Research, Austin, Texas, U.S.A. 1988-89
Director, Center for Fast Kinetics Research, Austin, Texas, U.S.A. 1989-94
Professor of Physical Chemistry, University of Texas, Austin, Texas, U.S.A. 1989-93
Professeur Invité, Université Louis Pasteur, Strasbourg, France 1993
Professeur Invité, School of Chemistry, E.H.I.C.S., Strasbourg, France 1994
Visiting Professor, Tokyo Metropolitan University, Tokyo, Japan 1995
Professeur, Université Louis Pasteur, Strasbourg, France 1995-99
Professor of Physical Chemistry, University of 缅北禁地, U.K. 1999-2019

Professor Emeritus, 缅北禁地, U.K. 2019-

Honours and Awards

Sir James Dewar Research Fellowship 1977
Royal Society (London) Visiting Research Scholarship 1982
Corday-Morgan Medal (RSC) 1984
Le Prix Grammaticakis-Neumann en Photochimie 1985

RSC Chemical Dynamics Award 2011

缅北禁地 Best Teacher Award 2016

UK Solar Fuels Lifetime Achievement Award 2018


Research

Research interests

The primary purpose behind the search for reaction mechanisms is to identify means by which to control, optimise and manipulate photochemical processes, with the ultimate ambition being to replace key reagents with improved prototypes. This chain of events can be illustrated by our recent work relating to stochastic super-resolution microscopy, where the dominant fluorescent species is a cyanine dye. We have developed an analytical protocol for measuring fluorescence probability at long wavelength (Pub. 11) and examined the role of competing photo-isomerisation with a well-known cyanine-conjugate (Pub. 7). On-going work, in collaboration with Aliaksandra Lisouskaya, is aimed at characterising spectroscopic and kinetic parameters for radicals derived from cyanine dyes of different conjugation length. A similar approach has been taken with singlet exciton fission occurring with TIPS-pentacene. The photophysical properties have been determined for the parent compound in dilute solution (Pub. 4) and, together with Tetsuro Majima, we have pioneered the use of pulse radiolysis to measure rates and yields of singlet fission in a related bichromophore (Pub. 10). A collaboration with Luis Arnaut has resulted in the first application of photoacoustic calorimetry to measure the triplet excitation energy of TIPS-pentacene and the bichromophore (Pub. 2). On-going research is aimed at resolving NIR phosphorescence from linear poly-acenes.

Concentration quenching is a long-standing problem in the field of molecular photophysics and was first explored in detail with solutions of chlorophyll. Covalently-linked bichromophores also exhibit fluorescence quenching due to the proximity effect and, in many cases, display pronounced excitonic coupling between the chromophores. These effects hinder the development of artificial light-harvesting arrays where high chromophore densities are critical. The degree of excitonic coupling can be controlled by careful attention to the mutual orientation of the respective transition dipole moment vectors. For example, in a collaboration with Raymond Ziessel, we found that these vectors are parallel, anti-parallel and obtuse, respectively, for the ortho-, para- and meta-bridged set of bis-boranils illustrated here. The para derivative is strongly fluorescent and does not show the strong polarity dependence observed for the mono-boranil complex. Similar protocols can be applied to crystalline samples where close proximity does not necessarily preclude emission. For example, the “half-BOPHY” species synthesized by Özgür Altan Bozdemir, is strongly fluorescent in the crystalline state but very weakly emissive in solution. Here, the difference relates to mobility of the transferrable proton. The detailed exploration of the luminescence properties of photonic crystals is an exciting new development in the field that could lead to the discovery of novel materials with unprecedented applications.

 

Selected recent publications

1) Algoazy, N., Knight, J.G., Waddell, P.G., Aerts, R., Herrebout, W., Al-Sharif, H.H.T., Karlsson, J.K.G., Harriman, A. Synthesis, Structure and Photophysical Properties of a New Class of Inherently Chiral Boron(III) Chelates—The tert-Leucine Complexes. (2021) Chemistry - A European Journal, 27 (16), pp. 5246-5258. DOI: 10.1002/chem.202005246

2) Karlsson, J.K.G., Atahan, A., Harriman, A., Tkachenko, N.V., Ward, A.D., Schaberle, F.A., Serpa, C., Arnaut, L.G. Singlet Exciton Fission and Associated Enthalpy Changes with a Covalently Linked Bichromophore  Comprising TIPS-Pentacenes Held in an Open Conformation. (2021) Journal of Physical Chemistry A, In press. DOI: 10.1021/acs.jpca.0c09961

3) Harriman, A., Bozdemir, Ö.A., Gultekin, D.D. Triplet distribution in a symmetrical zinc (II) porphyrin-BODIPY pentameric array. (2020) Journal of Physical Chemistry A, 124 (51), pp. 10736-10747. DOI: 10.1021/acs.jpca.0c09243

4) Schaberle, F.A., Serpa, C.; Arnaut, L.G., Ward, A.D., Karlsson, J.K.G., Atahan, A., Harriman, A. The Photophysical Properties of Triisopropylsilyl-ethynylpentacene—A Molecule with an Unusually Large Singlet-Triplet Energy Gap—In Solution and Solid Phases. (2020) Chemistry, 2 (2), pp. 545-564. DOI: org/10.3390/chemistry2020033

5) Al-Sharif, H.H.T., Ziessel, R., Waddell, P.G., Dixon, C., Harriman, A. Origin of Fluorescence from Boranils in the Crystalline Phase. (2020) J. Phys. Chem. A, 124 (11), pp. 2160–2172 DOI: 10.1021/acs.jpca.0c00905

6) Bozdemir, Ö.A., Al-Sharif, H.H.T., McFarlane, W., Waddell, P.G., Benniston, A.C., Harriman, A. Solid-State Emission from Mono- and Bichromophoric Boron Dipyrromethene (BODIPY) Derivatives and Comparison with Fluid Solution. (2019) Chemistry - A European Journal, 25 (68), pp. 15634-15645. DOI: 10.1002/chem.201903902

7) Karlsson, J.K.G., Laude, A., Hall, M.J., Harriman, A. Photo-isomerization of the Cyanine Dye Alexa-Fluor 647 (AF-647) in the Context of dSTORM Super-Resolution Microscopy. (2019) Chemistry - A European Journal, 25 (65), pp. 14983-14998. DOI: 10.1002/chem.201904117

8) Woodford, O.J., Ziessel, R., Harriman, A., Wills, C., Alsimaree, A.A., Knight, J.G. Optical spectroscopic properties recorded for simple BOPHY dyes in condensed media: The mirror-symmetry factor. (2019) Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 208, pp. 57-64. DOI: 10.1016/j.saa.2018.09.047

9) Woodford, O.J., Ziessel, R., Harriman, A. Photofading of an Extended BOPHY Chromophore Dispersed in Poly(methyl methacrylate) as a Chemical Actinometer. (2018) ChemPhotoChem, 2 (12), pp. 1046-1054. DOI: 10.1002/cptc.201800130

10) Karlsson, J.K.G., Atahan, A., Harriman, A., Tojo, S., Fujitsuka, M., Majima, T. Pulse Radiolysis of TIPS-Pentacene and a Fluorene-bridged Bis(pentacene): Evidence for Intramolecular Singlet-Exciton Fission. (2018) Journal of Physical Chemistry Letters, 9 (14), pp. 3934-3938. DOI: 10.1021/acs.jpclett.8b02006

11) Karlsson, J.K.G., Woodford, O.J., Mustroph, H., Harriman, A. Cyanine dyes as ratiometric fluorescence standards for the far-red spectral region. (2018) Photochemical and Photobiological Sciences, 17 (1), pp. 99-106. DOI: 10.1039/c7pp00333a

12) Harriman, A. Electrochemical catalysts to meet the challenge for sustainable fuel production from renewable energy. (2021) Current Opinion in Green and Sustainable Chemistry, in press. https://authors.elsevier.com/sd/article/S2452-2236(21)00048-1

13) Al-Sharif, H.H.T., Harriman, A. Bio-inspired artificial light-harvesting arrays based on boron(III)-chelates. (2021) Recent Advances in Boron-Containing Materials. IntechOpen. DOI: 10.5772/intechopen.91853

 

Teaching

No longer involved in undergraduate teaching, pedagogical matters take the form of writing a monograph on Colligative Properties, with lots of example calculations. There is also time to learn how to apply matrix theory and phasor methods for better representing multi-component photophysical processes. A book on Artificial Light-Harvesting Networks is slowly taking shape. I am actively involved in Advisory Boards, Editorial Boards and Review Boards.


Publications

  • Articles

    • Gultekin DD, Khan R, Karlsson JKG, Tkachenko NV, Acar M, Bozdemir OA, Harriman A. . Chemistry - A European Journal 2025, 31(30), e202500810.
    • Waly SM, Benniston AC, Harriman A. . Chemical Science 2024, 15(5), 1657-1671.
    • Bozdemir OA, Woodford OJ, Waddell PG, Harriman A. . Chemistry - A European Journal 2023, 29(31), e202300216.
    • Waly SM, Karlsson JKG, Waddell PG, Benniston AC, Harriman A. . The Journal of Physical Chemistry Part A 2022, 126(9), 1530-1541.
    • Algoazy N, Knight JG, Waddell PG, Aerts R, Herrebout W, Al-Sharif HHT, Karlsson JKG, Harriman A. . Chemistry: A European Journal 2021, 27(16), 5246-5258.
    • Karlsson JKG, Atahan A, Harriman A, Tkachenko NV, Ward AD, Schaberle FA, Serpa C, Arnaut LG. . Journal of Physical Chemistry A 2021, 125(5), 1184–1197.
    • Bozdemir OA, Gultekin DD, Harriman A. . Journal of Physical Chemistry A 2020, 124(51), 10736–10747.
    • Al-Sharif HHT, Ziessel R, Waddell PG, Dixon C, Harriman A. . Journal of Physical Chemistry A 2020, 124(11), 2160-2172.
    • Bozdemir OA, Al-Sharif HHT, McFarlane W, Waddell PG, Benniston AC, Harriman A. . Chemistry - A European Journal 2019, 25(68), 15634-15645.
    • Harriman A, Karlsson JKG, Laude A, Hall MJ. . Chemistry - A European Journal 2019, 25(65), 14983-14998.
    • Woodford OJ, Ziessel R, Harriman A. . ChemPhotoChem 2019, 2(12), 1046-1054.
    • Nassar SJM, Sirbu D, Harriman A. . Photochemical & Photobiological Sciences 2019, 18(12), 2875-2883.
    • Woodford OJ, Ziessel R, Harriman A, Wills C, Alsimaree AA, Knight JG. . Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2019, 208, 57-64.
    • Ziessel R, Stachelek P, Harriman A, Hedley GJ, Roland T, Ruseckas A, Samuel IDW. . The Journal of Physical Chemistry A 2018, 122(18), 4457-4447.
    • Sirbu D, Woodford OJ, Benniston AC, Harriman A. . Photochemical and Photobiological Sciences 2018, 17(6), 750-762.
    • Sirbu D, Karlsson JKG, Harriman A. . Journal of Physical Chemistry A 2018, 122(47), 9160-9170.
    • Woodford OJ, Stachelek P, Ziessel R, Algoazy N, Knight JG, Harriman A. . New Journal of Chemistry 2018, 42(7), 4835-4842.
    • Karlsson JKG, Woodford OJ, Mustroph H, Harriman A. . Photochemical and Photobiological Sciences 2018, 17(1), 99-106.
    • Stachelek P, Alsimaree AA, Alnoman RB, Harriman A, Knight JG. . The Journal of Physical Chemistry 2017, 121(10), 2096-2107.
    • Alnoman RB, Stachelek P, Knight JG, Harriman A, Waddell PG. . Organic and Biomolecular Chemistry 2017, 15(36), 7643-7653.
    • Al-Aqar R, Benniston AC, Harriman A, Perks T. . ChemPhotoChem 2017, 1(5), 198-205.
    • Sirbu D, Benniston AC, Harriman A. . Organic Letters 2017, 19(7), 1626-1629.
    • Karlsson JKG, Woodford OJ, Al-Aqar R, Harriman A. . Journal of Physical Chemistry A 2017, 121(45), 8569-8576.
    • Arranja C, Aguiar A, Encarnação T, Fonseca S, Justino L, Castro R, Benniston AC, Harriman A, Burrows H, Sobrala AJFN. . Journal of Molecular Structure 2017, 1146, 62.
    • Thakare S, Stachelek P, Mula S, More AB, Chattopadhyay S, Ray AK, Sekar N, Ziessel R, Harriman A. . Chemistry: A European Journal 2016, 22(40), 14356-14366.
    • Karlsson JKG, Harriman A. . Journal of Physical Chemistry A 2016, 120(16), 2537-2546.
    • Al-Aqar R, Atahan A, Benniston AC, Perks T, Waddell PG, Harriman A. . Chemistry: A European Journal 2016, 22(43), 15420-15429.
    • Stachelek P, Harriman A. . Journal of Physical Chemistry A 2016, 120(41), 8104-8113.
    • Hedley GJ, Ruseckas A, Benniston AC, Harriman A, Samuel IDW. . Journal of Physical Chemistry A 2015, 119(51), 12665-12671.
    • Harriman A, Stachelek P, Sutter A, Ziessel R. . Photochemical Photobiological Sciences 2015, 14(6), 1100-1109.
    • Azizi S, Ulrich G, Guglielmino M, le Calvé S, Hagon JP, Harriman A, Ziessel R. . Journal of Physical Chemistry A 2015, 119(1), 39-49.
    • Alamiry MAH, Harriman A, Haefele A, Ziessel R. . ChemPhysChem 2015, 16(9), 1867-1872.
    • Harriman A. . Chemical Communications 2015, 51(59), 11745-11756.
    • Harriman A, Stachelek P, Sutter A, Ziessel R. . Physical Chemistry Chemical Physics 2015, 17(39), 26175-26182.
    • Al-Aqar R, Avis D, Benniston AC, Harriman A. . RSC Advances 2014, 4(95), 53072-53078.
    • Harriman A. . European Journal of Inorganic Chemistry 2014, (4), 573-580.
    • Barba-Bon A, Costero AM, Gil S, Harriman A, Sancenon F. . Chemistry - A European Journal 2014, 20(21), 6339-6347.
    • Bahaidarah E, Harriman A, Stachelek P, Rihn S, Heyer E, Ziessel R. . Photochemical & Photobiological Sciences 2014, 13(10), 1397-1401.
    • Nano A, Ziessel R, Stachelek P, Alamiry MAH, Harriman A. . ChemPhysChem 2014, 15(1), 177-186.
    • Nano A, Retailleau P, Hagon J, Harriman A, Ziessel R. . Physical Chemistry Chemical Physics 2014, 16(21), 10187-10198.
    • Harriman A, Alamiry MAH, Hagon JP, Hablot D, Ziessel R. . Angewandte Chemie: International Edition 2013, 52(26), 6611-6615.
    • Hablot D, Ziessel R, Alamiry MAH, Bahraidah E, Harriman A. . Chemical Science 2013, 4(1), 444-453.
    • Alamiry MAH, Bahraidah E, Harriman A, Olivier JH, Ziessel R. . Pure and Applied Chemistry 2013, 85(7), 1349-1365.
    • Nano A, Ziessel R, Stachelek P, Harriman A. . Chemistry - A European Journal 2013, 19(40), 13528-13537.
    • Ziessel R, Ulrich G, Haefele A, Harriman A. . Journal of the American Chemical Society 2013, 135(30), 11330-11344.
    • Olivier JH, Barbera J, Bahaidarah E, Harriman A, Ziessel R. . Journal of the American Chemical Society 2012, 134(14), 6100-6103.
    • Alamiry MAH, Hagon JP, Harriman A, Bura T, Ziessel R. . Chemical Science 2012, 3(4), 1041-1048.
    • Alamiry MAH, Benniston AC, Copley G, Harriman A. . RSC Advances 2012, 2(5), 1936-1941.
    • Alamiry MAH, Bahaidarah E, Harriman A, Bura T, Ziessel R. . RSC Advances 2012, 2(26), 9851-9859.
    • Alamiry MAH, Benniston AC, Harriman A. . Journal of Physical Chemistry Part B 2012, 116(1), 253-260.
    • Iehl J, Nierengarten JF, Harriman A, Bura T, Ziessel R. . Journal of the American Chemical Society 2012, 134(2), 988-998.
    • Hablot D, Harriman A, Ziessel R. . Angewandte Chemie: International Edition 2011, 50(34), 7833-7836.
    • Benniston AC, Copley G, Harriman A, Ryan R. . Journal of Materials Chemistry 2011, 21(8), 2601-2608.
    • Stewart B, Harriman A, Higham LJ. . Organometallics 2011, 30(20), 5338-5343.
    • Le Pleux L, Pellegrin Y, Blart E, Odobel F, Harriman A. . Journal of Physical Chemistry A 2011, 115(20), 5069-5080.
    • Alamiry MAH, Benniston AC, Copley G, Harriman A, Howgego D. . Journal of Physical Chemistry A 2011, 115(44), 12111-12119.
    • Benniston AC, Clift S, Harriman A. . Journal of Molecular Structure 2011, 985(2-3), 346-354.
    • Benniston AC, Harriman A, Yang S, Harrington RW. . Tetrahedron Letters 2011, 52(41), 5315-5318.
    • Hedley GJ, Ruseckas A, Harriman A, Samuel IDW. . Angewandte Chemie: International Edition 2011, 50(29), 6634-6637.
    • Ziessel R, Harriman A. . Chemical Communications 2011, 47(2), 611-631.
    • Ziessel R, Rihn S, Harriman A. . Chemistry: A European Journal 2010, 16(39), 11942-11953.
    • Benniston AC, Harriman A, Whittle VL, Zelzer M. . European Journal of Organic Chemistry 2010, (3), 523-530.
    • Harriman A, Ziessel R. . Photochemical & Photobiological Sciences 2010, 9(7), 960-967.
    • Benniston AC, Harriman A, Whittle VL, Zelzer M, Harrington RW, Clegg W. . Photochemical and Photobiological Sciences 2010, 9(7), 1009-1017.
    • Mula S, Elliott K, Harriman A, Ziessel R. . Journal of Physical Chemistry Part A 2010, 114(39), 10515-10522.
    • Benniston AC, Copley G, Harriman A, Howgego D, Harrington RW, Clegg W. . Journal of Organic Chemistry 2010, 75(6), 2018-2027.
    • Benniston AC, Harriman A, Li PY. . Journal of the American Chemical Society 2010, 132(1), 26-27.
    • Ziessel R, Ulrich G, Harriman A, Alamiry MAH, Stewart B, Retailleau P. . Chemistry: A European Journal 2009, 15(6), 1359-1369.
    • Ziessel R, Allen BD, Rewinska DB, Harriman A. . Chemistry: A European Journal 2009, 15(30), 7382-7393.
    • Harriman A, Mallon LJ, Elliott KJ, Haefele A, Ulrich G, Ziessel R. . Journal of the American Chemical Society 2009, 131(37), 13375-13386.
    • Harriman A, Elliott KJ, Alamiry MAH, Le Pleux L, Severac M, Pellegrin Y, Blart E, Fosse C, Cannizzo C, Mayer CR, Odobel F. . Journal of Physical Chemistry C 2009, 113(14), 5834-5842.
    • Ziessel R, Alamiry MAH, Elliott KJ, Harriman A. . Angewandte Chemie: International Edition 2009, 48(15), 2772-2776.
    • Harriman A, Mallon LJ, Goeb S, Ulrich G, Ziessel R. . Chemistry: A European Journal 2009, 15(18), 4553-4564.
    • Ziessel R, Ulrich G, Elliott KJ, Harriman A. . Chemistry: A European Journal 2009, 15(20), 4980-4984.
    • Odobel F, Severac M, Pellegrin Y, Blart E, Fosse C, Cannizzo C, Mayer CR, Eliott KJ, Harriman A. . Chemistry: A European Journal 2009, 15(13), 3130-3138.
    • Doherty S, Smyth CH, Harriman A, Harrington RW, Clegg W. . Organometallics 2009, 28(3), 888-895.
    • Ziessel R, Retailleau P, Elliott KJ, Harriman A. . Chemistry: A European Journal 2009, 15(40), 10369-10374.
    • Benniston AC, Allen BD, Harriman A, Llarena I, Rostron JP, Stewart B. . New Journal of Chemistry 2009, 33(2), 417-427.
    • Elliott KJ, Harriman A, Le Pleux L, Pellegrin Y, Blart E, Mayer CR, Odobel F. . Physical Chemistry Chemical Physics 2009, 11(39), 8767-8773.
    • Alamiry MAH, Harriman A, Mallon LJ, Ulrich G, Ziessel R. . European Journal of Organic Chemistry 2008, (16), 2774-2782.
    • Benniston AC, Harriman A, Li P, Patel PV, Sams CA. . Chemistry: A European Journal 2008, 14(6), 1710-1717.
    • Alamiry MAH, Benniston AC, Copley G, Elliott KJ, Harriman A, Stewart B, Zhi Y-G. . Chemistry of Materials 2008, 20(12), 4024-4032.
    • Benniston AC, Copley G, Harriman A, Rewinska DB, Harrington RW, Clegg W. . Journal of the American Chemical Society 2008, 130(23), 7174-7175.
    • Harriman A, Mallon LJ, Ulrich G, Ziessel R. . ChemPhysChem 2007, 8(8), 1207-1214.
    • Benniston AC, Harriman A, Howell SL, Li P, Lydon DP. . Journal of Organic Chemistry 2007, 72(3), 888-897.
    • Benniston AC, Harriman A, Rewinska DB, Yang S, Zhi Y-G. . Chemistry - A European Journal 2007, 13(36), 10194-10203.
    • Benniston AC, Harriman A, Howell SL, Sams CA, Zhi Y-G. . Chemistry - A European Journal 2007, 13(16), 4665-4674.
    • Benniston AC, Harriman A, Llarena I, Sams CA. . Chemistry of Materials 2007, 19(8), 1931.
    • Benniston AC, Harriman A, Llarena I, Sams CA. . Chemistry of Materials 2007, 19(8), 1931-1938.
    • Allen BD, Benniston AC, Harriman A, Llarena I, Sams CA. . Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment and General Theory 2007, 111(14), 2641-2649.
    • Harriman A, Izzet G. . Physical Chemistry Chemical Physics 2007, 9(8), 944-948.
    • Benniston AC, Harriman A, Pariani C, Sams CA. . Journal of Physical Chemistry A 2007, 111(37), 8918-8924.
    • Harriman A, Mallon LJ, Stewart B, Ulrich G, Ziessel R. . European Journal of Organic Chemistry 2007, (19), 3191-3198.
    • Benniston AC, Harriman A, Li P, Rostron JP, Harrington RW, Clegg W. . Chemistry - A European Journal 2007, 13(28), 7838-7851.
    • Harriman A, Mallon LJ, Goeb S, Ziessel R. . Physical Chemistry Chemical Physics 2007, 9(38), 5199-5201.
    • Van Ramesdonk HJ, Bakker BH, Groeneveld MM, Verhoeven JW, Allen BD, Rostron JP, Harriman A. . Journal of Physical Chemistry A 2006, 110(49), 13145-13150.
    • Harriman A, Rostron SA, Khatyr A, Ziessel R. . Faraday Discussions 2006, 131, 377-391.
    • Goze C, Ulrich G, Mallon LJ, Allen BD, Harriman A, Ziessel R. . Journal of the American Chemical Society 2006, 128(31), 10231-10239.
    • Harriman A, Izzet G, Ziessel R. . Journal of the American Chemical Society 2006, 128(33), 10868-10875.
    • Harriman A, Izzet G, Goeb S, De Nicola A, Ziessel R. . Inorganic Chemistry 2006, 45(24), 9729-9741.
    • Benniston AC, Chapman GM, Harriman A, Sams CA. . Inorganica Chimica Acta 2006, 359(3), 753-758.
    • Benniston AC, Harriman A, Pariani C, Sams CA. . Physical Chemistry Chemical Physics 2006, 8(17), 2051-2057.
    • Harriman A, Rostron JP, Cesario M, Ulrich G, Ziessel R. . Journal of Physical Chemistry A 2006, 110(26), 7994-8002.
    • Allen BD, Benniston AC, Harriman A, Mallon LJ, Pariani C. . Physical Chemistry Chemical Physics 2006, 8(35), 4112-4118.
    • Benniston AC, Harriman A, Li P, Patel PV, Rostron JP, Sams CA. . Journal of Physical Chemistry A 2006, 110(32), 9880-9886.
    • Benniston AC, Harriman A, Li P, Patel PV, Sams CA. . Journal of Organic Chemistry 2006, 71(9), 3481-3493.
    • Allen BD, Benniston AC, Harriman A, Rostron SA, Yu C. . Physical Chemistry Chemical Physics 2005, 7(16), 3035-3040.
    • Benniston AC, Harriman A, Li P, Patel PV, Sams CA. . Physical Chemistry Chemical Physics 2005, 7(21), 3677-3679.
    • Benniston AC, Harriman A, Rostron JP. . Physical Chemistry Chemical Physics 2005, 7(16), 3041-3047.
    • Benniston AC, Harriman A, Li P, Sams CA. . Journal of the American Chemical Society 2005, 127(8), 2553-2564.
    • Benniston AC, Chapman GM, Harriman A, Rostron SA. . Inorganic Chemistry 2005, 44(11), 4029-4036.
    • Harriman A, Mayeux A, Stroh C, Ziessel R. . Dalton Transactions 2005, (17), 2925-2932.
    • Verhoeven JW, van Ramesdonk HJ, Zhang H, Groeneveld MM, Benniston AC, Harriman A. . International Journal of Photoenergy 2005, 7(2), 103-108.
    • Harriman A, Mehrabi M, Maiya BG. . Photochemical and Photobiological Sciences 2005, 4(1), 47-53.
    • Ziessel R, Goze C, Ulrich G, Cesario M, Retailleau P, Harriman A, Rostron JP. . Chemistry: A European Journal 2005, 11(24), 7366-7378.
    • Benniston AC, Harriman A, Li P, Rostron JP, Verhoeven JW. . Chemical Communications 2005, (21), 2701-2703.
    • Benniston AC, Harriman A, Li P, Rostron JP, Verhoeven JW. . Chemical Communications 2005, (21), 2701-2703.
    • Rostron JP, Ulrich G, Retailleau P, Harriman A, Ziessel R. . New Journal of Chemistry 2005, 29(10), 1241-1244.
    • Benniston AC, Harriman A, Lawrie DJ, Mehrabi M. . European Journal of Organic Chemistry 2005, (7), 1384-1391.
    • Benniston AC, Harriman A, Li P, Rostron JP. . Tetrahedron Letters 2005, 46(43), 7291-7293.
    • Benniston AC, Harriman A, Li P, Sams CA. . Journal of Physical Chemistry A 2005, 109(10), 2302-2309.
    • Benniston AC, Harriman A, Li P, Rostron JP, Van Ramesdonk HJ, Groeneveld MM, Zhang H, Verhoeven JW. . Journal of the American Chemical Society 2005, 127(46), 16054-16064.
    • Benniston AC, Harriman A, Patel PV, Sams CA. . European Journal of Organic Chemistry 2005, 2005(21), 4680-4686.
    • Benniston AC, Harriman A, Lawrie DJ, Mehrabi M, Russell OD. . Inorganica Chimica Acta 2005, 358(12), 3483-3490.
    • Amini A, Harriman A, Mayeux A. . Physical Chemistry Chemical Physics 2004, 6(6), 1157-1164.
    • Benniston AC, Harriman A, Lawrie DJ, Mayeux A. . Physical Chemistry Chemical Physics 2004, 6(1), 51-57.
    • Benniston AC, Harriman A, Lawrie DJ, Rostron SA. . Tetrahedron Letters 2004, 45(12), 2503-2506.
    • Benniston AC, Harriman A, McCulloch IE, Mehrabi M, Rostron SA, Sams CA. . Journal of Photochemistry and Photobiology A: Chemistry 2004, 163(1-2), 61-67.
    • Benniston AC, Harriman A, Mehrabi M, Rostran S, McCulloch IE, Sams C. . Journal of Photochemistry and Photobiology A: Chemistry 2004, 163(1-2), 61-67.
    • Benniston AC, Harriman A, Li PY, Sams CA, Ward MD. . Journal of the American Chemical Society 2004, 126(42), 13630-13631.
    • Benniston AC, Chapman GM, Harriman A, Mehrabi M. . Journal of Physical Chemistry A 2004, 108(42), 9026-9036.
    • Benniston AC, Chapman G, Harriman A, Mehrabi M, Sams CA. . Inorganic Chemistry 2004, 43(14), 4227-4233.
    • Benniston AC, Harriman A, Romero FM, Ziessel R. . Dalton Transactions 2004, (8), 1233-1238.
    • Benniston AC, Harriman A, Li P, Sams CA. . Physical Chemistry Chemical Physics 2004, 6(5), 875-877.
    • Amini A, Harriman A. . Journal of Physical Chemistry A 2004, 108(7), 1242-1249.
    • Benniston AC, Harriman A, Lawrie DJ, Rostron SA. . European Journal of Organic Chemistry 2004, 2004(10), 2272-2276.
    • Benniston AC, Clegg W, Harriman A, Harrington RW, Li P, Sams C. . Tetrahedron Letters 2003, 44(13), 2665-2667.
    • Benniston AC, Davies M, Harriman A, Sams C. . Journal of Physical Chemistry A 2003, 107(23), 4669-4675.
    • Amini A, Harriman A. . Physical Chemistry Chemical Physics 2003, 5(7), 1344-1351.
    • Amini A, Harriman A. . Physical Chemistry Chemical Physics 2003, 5(20), 4556-4562.
    • Charbonniere LJ, Ziessel RF, Sams CA, Harriman A. . Inorganic Chemistry 2003, 42(11), 3466-3474.
    • Amini A, Harriman A. . Journal of Photochemistry and Photobiology C: Photochemistry Reviews 2003, 4(2), 155-177.
    • Benniston AC, Harriman A, Li P, Sams CA. . Tetrahedron Letters 2003, 44(22), 4167-4169.
    • Benniston AC, Harriman A, Lawrie DJ, Mayeux A, Rafferty K, Russell OD. . Dalton Transactions 2003, (24), 4762-4769.
    • Harriman A, Mayeux A, De Nicola A, Ziessel R. . Physical Chemistry Chemical Physics 2002, 4(11), 2229-2235.
    • Armspach D, Matt D, Harriman A. . European Journal of Inorganic Chemistry 2000, 2000(6), 1147-1150.
    • Benniston AC, Gardner S, Farrugia LJ, Harriman A. . Journal of Chemical Research 2000, 2000(8), 360-361.
    • Knight JG, Doherty S, Harriman A. . Organometallics 2000, 19(24), 4957-4967.
    • Juris A, Prodi L, Harriman A, Ziessel R, Hissler M, El-ghayoury A, Wu F, Riesgo EC, Thummel RP. . Inorganic Chemistry 2000, 39(16), 3590-3598.
    • El-ghayoury A, Harriman A, Khatyr A, Ziessel R. . Journal of Physical Chemistry A 2000, 104(7), 1512-1523.
    • El-ghayoury A, Harriman A, Ziessel R. . Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory 2000, 104(33), 7906-7915.
    • Ziessel R, Harriman A, El-ghayoury A, Douce L, Leize E, Nierengarten H, Van Dorsselaer A. . New Journal of Chemistry 2000, 24(10), 729-732.
    • Dieleman CB, Matt D, Harriman A. . European Journal of Inorganic Chemistry 2000, (5), 831-834.
    • Harriman A, Khatyr A, Ziessel R, Benniston AC. . Angewandte Chemie International Edition 2000, 39(23), 4287-4290.
    • Harriman A, Khatyr A, Ziessel R, Benniston AC. . Angewandte Chemie - International Edition 2000, 39(23), 4287-4290.
    • Harriman A, Ziessel R, Hissler M, Trompette O. . Journal of the American Chemical Society 1999, 121(11), 2516-2525.
    • Harriman A. . Angewandte Chemie-International Edition 1999, 38(7), 945-949.
    • Harriman A, Wipff G, Ziessel R, Hissler M. . Journal of the American Chemical Society 1999, 121(1), 14-27.

  • Book Chapters

    • Stewart B, Harriman A, Higham LJ. . In: Fairlamb, I.J.S., Lynam, J.M, ed. Specialist Periodical Reports: Organometallic Chemistry. London, UK: Royal Society of Chemistry, 2012, pp.36-47.
    • Harriman A, Khatyr A, Rostron SA, Ziessel R. . In: Schubert, US; Newkome, GR; Manners, I, ed. Metal-Containing and Metallosupramolecular Polymers and Materials. Washington DC: American Chemical Society, 2006, pp.72-85.

  • Conference Proceedings (inc. Abstract)

    • Benniston AC, Harriman A. . In: Coordination Chemistry Reviews: 17th International Symposium on Photochemistry and Photophysics of Coordination Compounds. 2008, Dublin, Ireland: Elsevier.

  • Editorials

    • Harriman A. . ChemPhotoChem 2019, 3(3), 120-121.
    • Harriman A. . Platinum Metals Review 2012, 56(1), 20-24.
    • Harriman A. . Chemistry World 2011, 8(2), 37.

  • Notes

    • Benniston AC, Harriman A, Verhoeven JW. . Physical Chemistry Chemical Physics 2008, 10(33), 5156-5158.
    • Verhoeven JW, Van Ramesdonk HJ, Groeneveld MM, Benniston AC, Harriman A. . ChemPhysChem 2005, 6(11), 2251-2260.

  • Reviews

    • Harriman A. . Johnson Matthey Technology Review 2016, 60(1), 55-58.
    • Ulrich G, Ziessel R, Harriman A. . Angewandte Chemie (International Edition) 2008, 47(7), 1184-1201.
    • Harriman A, Mallon L, Ziessel R. . Chemistry: A European Journal 2008, 14(36), 11461-11473.
    • Benniston AC, Harriman A. . Coordination Chemistry Reviews 2008, 252(23-24), 2528-2539.
    • Benniston AC, Harriman A. . Materials Today 2008, 11(12), 26-34.
    • Ziessel R, Ulrich G, Harriman A. . New Journal of Chemistry 2007, 31(4), 496-501.
    • Benniston AC, Harriman A. . Chemical Society Reviews 2006, 35(2), 169-179.
    • Amini A, Harriman A. . Journal of Photochemistry and Photobiology C: Photochemistry Reviews 2003, 4(2), 155-177.
    • Harriman A. . Photochemistry 2002, 33, 13-49.
    • Harriman A. Photophysical processes in condensed phases. Photochemistry 2001, 32, 13-46.